Zirconium tetrachloride revisited

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چکیده

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Vibrational Spectra, Assignments and Normal Coordinate Analyses for Crystalline Zirconium Tetrachloride and Tetrabromide

The structure of solid zirconium tetrachloride is known from X-ray studies[l] to consist of extended chains of distorted octahedra with two bridging chlorine atoms between adjacent zirconium atoms. Although the unit cell possesses a center of symmetry, the two pairs of bridging chlorine atoms attached to a given zirconium atom are not trans to each other. The factor group symmetry thus is C2h w...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section C Structural Chemistry

سال: 2018

ISSN: 2053-2296

DOI: 10.1107/s205322961800219x